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Delamination blisters,

with Pedro Reis, Dominic Vella, Arezki BoudaoudBenoit Roman

Delamination blisters are commonly observed when a thin layer deposited on a substrate happens to be compressed. This is for instance the case for a sticker on a window when sun heat tends to expend the sticker material. 

Although destructive in most practical applications, such blisters may be useful to develop stretchable electronic devices which could be used for medical applications or electronic paper for instance. Indeed, blister-shaped electronic circuits experience less mechanical stress when the substrate gets deformed.

Macroscopic experiments with well controlled and tunable physical parameters teach us what are the laws dictating the formation and the final size of such blisters.


image credit: D. Coveney, MIT

Click on the picture to watch the formation of blisters on a compressed substrate (1.7Mb)
Bibliography

Capillary Origami,

with Benoit Roman , Charlotte Py , Lionel Doppler, Paul Reverdy & Charles Baroud



What happens when a water droplet is deposited on a flexible sheet? Does the sheet spontaneously wrap the droplet? Yes, if driving capillary forces overtake the elastic bending resistance of the sheet (linked movie1). If the sheet is stiffer, the corners start bending but the sheet quickly reopens (linked movie 2).

What are geometrical shapes eventually obtained after the partial evaporation of the droplet? 
The final conformation is dictated by the initial cut of the sheet. Pyramids, cubes or quasi-spheres are obtained from triangles, crosses or flowers shapes, respectively.
Beyond scientific curiosity (the problem is in strong connection with Gauss classical theorema egregium on topology), we believe this
capillary origami mechanism to be relevant for building three dimensional micro-structures from two dimensional templates. At small scales capillary forces indeed dominate and minute droplets may serve as micro-pliers.

Click on the picture to watch the folding of an planar triangle into a pyramid (8Mb)

Bibliography


Wet hair,

with Benoit Roman , Charlotte Py , Arezki Boudaoud , Sébastien Neukirch & Charles Baroud



The hair of a dog coming out of a pond assemble into clumps giving him a spiny appearance. What is the number of hairs in a clump? The answer relies on a balance betwen capillary forces and elasticity of the hairs. More generally, the stiking of flexible elements dramatically damages mechanical microsystems or lung airways, but also allows beetles to climb on walls.

Click on the picture to watch the video (10Mb)

Bibliography

Windswept droplets,

with Marc Fermigier , François Besselièvre, Gabriel Amselem & A.Kevin Njifenju

   

A small droplet impacting a glass window usually remains stuck on the pane. How can we expel it? One possible solution consists in depositing a hydrophobic coating the glass surface. Another solution is to blow it out. We propose to explore this last solution (partly combined with the first one). What is the running speed of the droplet as a function of the wind velocity? Is there any threshold to allow its motion? How does the shape of the droplet evolve? Does it leave any tail and satellite droplets?

Gobbling droplets,

with Christian Clasen , Gareth McKinley & Vladimir Entov

 

A jet of liquid is unstable because of surface tension and usually breaks into small droplets. The addition of minute quantities of polymeric molecules provides an additive elastic stress which stabilizes the liquid column. In this situation the terminal droplet has the time to gobble many of its incoming neighbors before its detachment.

Click on the picture to watch the video (5.9Mb)



Spreading flowers,

with Angelina Aessopos , Vladimir Entov, Anette (Peko) Hosoi , Marc Fermigier & Gareth McKinley


The spreading of a droplet of food dye on a layer of semi-dilute polymer solution leads to a fingering pattern. Although Carlo Marangoni identified the motor of these phenomena as the contrast between the surface trensions of the diferent interfaces in the 1880's, the origin of these dendrites remains an open question.

Click on the picture to watch the video (6.5Mb)



Dripping of a jelly liquid,

with Christian Clasen , Gareth McKinley & Vladimir Entov

Concentrated surfactant solutions may exhibit particular molecular structures (“worm like micelles”) which lead to a jelly liquid. The material behaves as a soft elastic solid when a light stress is applied but flows as a liquid under higher stresses. 

When a droplet of such a liquid drips from a pipette, a long thread connects the droplet to the pipette and progressively necks and breaks down when the thread reaches a critical diameter.

Click on any picture to watch the video (2.2Mb).



Rolling Stones,  

with Jacqueline Ashmore , Howard Stone & Gareth McKinley

Once deposited on a tilted planar surface coated with some viscous liquid, a sphere rolls down and slides at the same time. Tire prints like patterns are formed behind the ball. 
An overhang situation is also possible: an heavy ball rolls down eventually without falling off, only hold by a liquid bridge!
This project has been inspired from nice experiments from A.Samadani and A.Kudrolli on granular media.

Click on the pictures to watch "stones" racing inside a rotating drum (2.7Mb)

Fingering instabilities in viscoelastic liquids, 

with Ryan Welsh & Gareth McKinley

The separation of two plates bridged by a thin layer of a viscoelastic liquid leads to complex instabilities. 
The experiment shown was done using a polystyrene Boger fluid characterized by a relaxation time of 3 min.

The larger fingering structure corresponds to a Saffman Taylor: a fluid of low viscosity (air) penetrate into a viscous liquid which generates viscous fingering. Elastic stresses in the solution are also induced when the polymeric molecules get stretched enough. They are responsible for the secondary structure which develops at larger strains.

The endplate diameter is 5mm, the initial gap between the endplate  is 0.1 mm and the Deborah number (relaxation time/experiment time) is 43.

Click on the picture to watch a video of this experiment (1.2Mb) .

 

Ganesha instability,

with Gareth McKinley & L.Mahadevan



Multi-walled nanotubes exhibits periodic ripples when they are bent. This instability essentially depends on the tubes geometry but not on the material properties. The same popliteal ripples are also observed with macroscopic rubber sheet scrolls or even on elephant trunks!


Super Hydrophobic Surfaces,

initially with David Quéré & Denis Richard,
more recently with G. McKinley, K.Lau, K.B.K. Teo, M. Chhowalla, G.A.J. Amaratunga and W.I. Milne

The combination of an hydrophobic material and and rough surface can lead to super hydrophobic surfaces. A water droplet deposited on such a substrate remains at rest on the tops of the roughness which widely reduces the contact area of the liquid with the solid. The drop is mainly in contact with air and keeps the shape it would have in the air.

Click on the picture to watch a video (2Mb) of the dynamics of water on such a surface.

Click here to watch a water droplet boucing on a superhydrophobic surface (7Mb)

Bibliography


The shape of Tektites,

with Tim Kreider, John Bush , Linda Elkins Tanton , Pascale Aussillous and David Quéré

Tektites are believed to be the "splashes" from the impact of big meteorites on the Earth. The molten silica material (mainly from terrestrial origin) would be ejected with some spinning motion which deforms the liquid drops. These rotating shapes are often frozen by the cooling down of the liquid during its flight.
 


Liquid trains in a tube,

with David Quéré

If two adjacent liquids are introduced in a capillary tube, a spontaneous motion of this bislug is generally observed when the tube is hold horizontally. This flow relies on the asymmetry of the system: capillary forces on the three menisci do not necessarily balance and their contrast drives the bislug.
This motion is not perpetual since a trail of the liquids is left behind the bislug which is consumed during its displacement.

Click on the picture to watch a video of a bislug experiment (3.3Mb) .

Bibliography


Ex-vivo rheology of spider silk,

with  Nikola Kojić, Christian Clasen Gareth McKinley

Nephila clavipes spider (female) and one of her major ampulate glands

Although spider silk has been revered during last decade for its unmatched mechanical properties, very little is known about the rheological properties of the spinning dope. Determining the shear and extensionnal rheology of the spinning dope should give some guidance to understand the complex spinning process occurring along the spider spinning canal .